Manual Name Reactions for Homologation, Part I

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Arndt-Eistert Synthesis

Armed with this invaluable resource, both students and professionals will have at their fingertips a comprehensive guide to important mechanisms and phenomena in homologation. The following ISBNs are associated with this title:. ISBN - On the Content tab, click to select the Enable JavaScript check box. Click OK to close the Options popup.

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Name Reactions in Heterocyclic Chemistry II

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Corey , Nobel Prize Laureate An invaluable guide to name reactions and reagents for homologations Name Reactions for Homologations, Part II of Wiley's Comprehensive Name Reactions series comprises a comprehensive treatise on name reactions for homologations. In addition to the use of the names of chemists, we also have groundbreaking reactions that come to be known by abbreviations of a descriptive name, such as "RCM" ring-closing metathesis or INOC intramolecular nitrile oxide cyclization.

We seldom use the name of the chemist who developed RCM Robert Grubbs to refer to the reaction, but his contribution is instead acknowledged by applying his name to the ruthenium-catalysts used. Thus, we speak of the "Grubbs catalyst" or "2nd generation Grubbs catalyst". Besides names such as "RCM", some frequently used reactions are named for structural features of the precursor or product. Examples include the "aldol reaction" "aldol" is an abbreviation of a compound that contains both aldehyde and alcohol functionalities or the "pinacol rearrangement".

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Name Reactions

As mentioned above, name reactions are used to refer to groundbreaking reactions or the associated mechanisms or principles that are worthwhile knowing and keeping straight. Just as physicians must learn the names of organs and geologists the names of minerals, chemists or students of chemistry use name reactions as a way to organize their knowledge and communicate about chemical transformations. In laboratory discussions, people very often use name reactions to refer to experiments they are running or the chemical problems they are investigating. The name reaction is a type of shorthand that avoids the need to give a lengthier explanation of the features of a particular transformation of interest.

Mentioning the name reaction allows a knowledgeable listener to bring to mind the possible substrates, reaction conditions, or mechanistic details.


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Everyone in the field is expected to know a basic set of name reactions by heart, and this makes discussions less time-consuming. In this way, name reactions have become part of the shared vocabulary of organic synthesis chemists.

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Such recognition can signal that a listener or job candidate has command of a particular area of chemistry. This means that he or she would be capable of understanding details of the synthetic routes in the work described, and could possibly develop alternatives. Site Search any all words.